Chemical Engineering Thermodynamics

Basic concepts in Thermodynamics, laws of Thermodynamics and their applications in engineering problems, steady flow processes, unsteady flow processes, entropy and entropy balance for open systems

An introduction to vapor-liquid Equilibria, qualitative behavior of the vapour-liquid equilibria (VLE), simple models for vapor-liquid equilibria, Raoults law, Henry’s law, Dew point and Bubble point calculations, VLE by modified Raoults law, the gamma/Philips formulation of VLE

Solution Thermodynamics- Fundamental property relay, Chemical potential, partial molar Property, partial properties in binary solutions, equations relating molar and partial molar properties, criteria for Equilibrium between phases in multicomponent non reacting systems in terms of chemical potential, fugacity and fugacity coefficient for pure species, fugacity and fugacity coefficient for species in solutions, fugacity coefficient from the virial equation of state and generalized correlations

Solution Thermodynamics Applications- ideal solution, Lewis rand all rule, excess Gibbs energy and activity coefficient, Liquid phase properties from VLE data, Excess Gibbs energy data reduction, Thermodynamic consistency of phase equilibria, applications of the correlations and prediction of phase equilibria, models for excess Gibbs energy, Property change of mixing

Chemical Reaction Equilibria-The reaction coordinate, standard Gibbs free energy change and Equilibrium constant, Effect of temperature on Equilibrium constant, evaluation of Equilibrium constant, relation of equilibrium constants to composition for gas phase and liquid phase reactions, Equilibrium conversion for single reaction, Thermodynamic analysis of simultaneous reactions TOTAL