BCH063

Colloid Surface & Interfacial Phenomena

L-T-P3-0-0 Credits3 Session2024-25 TypeTheory
Appears in 1 semester

B.Tech Chemical Engineering · Sem 6 (Departmental Elective-III)

Syllabus

5 units · 40 lecture hours
Unit1

Unit 1

8 hrs

Introduction of colloidal systems and their classification, origin of charge on colloidal particles, stabilization of different colloidal system by surfactants, solubilisation, emulsions, microemulsions, HLB, micelle formation by surfactants, thermodynamic parameters of micellization, emulsification by surfactants, micellar catalysis, synergism in mixture of two surfactants.

Unit2

Unit 2

6 hrs

Fundamental aspects of colloidal suspensions, surface tension, wetting, surfactant adsorption, self-assembly, and inter particle interactions, as well as the importance of these phenomena to consumer, industrial, and biomedical applications.

Unit3

Unit 3

8 hrs

Intermolecular, nanoscale and interfacial forces in organic, polymeric, biological and aqueous systems. Van der waals, electrostatic double layer, acid-base interactions including hydrophobic attraction and hydration pressure.

Unit4

Unit 4

10 hrs

Mesoscale thermodynamics and Mesoscale phenomena in soft matter & applications Gibb’s treatment of interfaces, concept of excess concentration, variation of interfacial tension with surface concentration, Adhesion, wetting, nucleation, flotation, patterning of soft material by self organization and other techniques.

Unit5

Unit 5: Nanofluidics and Advanced & Functional Interfaces

8 hrs

Stability of thin (< 100 nm) film, self-organization in confined systems, mesoscale patterning. Super hydrophobicity, functions coatings, structural colours, nano-adhesives, nanocomposites.

Course Objectives3 points
  • To introduce students to the fundamentals of colloidal and interfacial phenomena
  • Exposing them to a broad selection of topics, including colloidal suspensions, Intermolecular, nanoscale and interfacial forces systems
  • To provide knowledge about the importance of the surface properties.
Course Outcomes (COs)6 outcomes

After completion of the course student will be able to:

  1. CO1Understand the classification and stabilization mechanisms of colloidal systems using surfactants.
  2. CO2Analyze surfactant behavior in micellization, emulsification, and micellar catalysis.
  3. CO3Explore fundamental aspects of colloidal suspensions, including surface tension and surfactant adsorption.
  4. CO4Evaluate intermolecular and interfacial forces in organic, polymeric, and biological systems.
  5. CO5Apply mesoscale thermodynamics to soft matter phenomena, such as adhesion and wetting.
  6. CO6Investigate nanofluidics and advanced interfaces, focusing on thin film stability and functional coatings.

REFERENCE BOOKS

  1. S.NO

Books

  1. YEAR OF PUBLICATI ON/ REPRINT
  2. Surfactants and interfacial phenomena, Milton J. Rosen, 5th edition 2012
  3. Principles of Colloid and Surface Chemistry, Paul C. Hiemenz, Marcel DEker,2nd edition 2007
  4. Physical Chemistry of Surfaces, Arthur W. Adamson, 6th Edition Wiley. 1997
  5. Foundations of Colloid Science, Robert J. Hunter, 2nd edition (2001) Oxford University Press 2001
  6. Colloidal Dispersions, W. B. Russel, D. A. Saville, and W, R. Schowalter, Cambridge University Press . 3rd Edition 2012 2012
  7. Intermolecular and Surface forces, Jacon N. Israelachvili, Academic Press, 3rd edition 2011
  8. Interfacial Forces in Aqueous Media, Carel J. van Oss, Marcel Dekker or Taylor Francis. 2nd edition 2006

Official AKTU syllabus

This subject is on page 53, 54 of the original AKTU PDF.

Official AKTU syllabus PDF ↗